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I use Pocket Informant as well. Pocket Informant supports multiple calendars and you need to make sure the new event you are creating gets written to the iOS calendar. Make sure your Pocket Informant settings are configured for this.

Once you have them setup correctly and you create a calendar item in Pocket Informant, then go to the Apple provided calendar application. If you can see your event there, then that confirms that Pocket Informant is writing to the correct calendar. Then it should show in Omnifocus as well.