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You can't use Bonjour for syncing without the desktop app, which provides the server. Other than that, it's a snap to set up -- you just start up the desktop app, go to the Sync preferences, turn on Bonjour syncing, set a password, and click the "share my settings" button. Then you go to the settings page on the iPhone, tell it you want Bonjour syncing, and click the Get Settings from Mac button. You'll be presented with a list of all of the OmniFocus apps the iPhone found broadcasting their settings (likely to be just yours!), you choose the one you want, and you're done. About the only place things can go wrong is if the Mac and the iPhone aren't on the same network, which will prevent the Bonjour discovery protocols from working.